Published April 29, 2026 | Version v1.0
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OKAKER

  • 1. University of Strathclyde

Description

Excited state energies, ORCA output file and optimised ground state geometry of OKAKER. Full dataset available here: BenchmarkSet1500.csv.

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Additional details

Related works

Is supplement to
Journal article: 10.1016/j.tet.2010.11.110 (DOI)

Domain Specific Metadata

 

Excited States Properties

Property Value
E(S1) SA-CASSCF / eV 4.531
E(S2) SA-CASSCF / eV 5.168
E(T1) SA-CASSCF / eV 2.162
E(T2) SA-CASSCF / eV 4.223
f(S1) SA-CASSCF 0.03582616
f(S2) SA-CASSCF 0.268769669
E(S1) SC-NEVPT2 / eV 4.119
E(S2) SC-NEVPT2 / eV 4.405
E(T1) SC-NEVPT2 / eV 2.462
E(T2) SC-NEVPT2 / eV 3.989
f(S1) SC-NEVPT2 0.034834432
f(S2) SC-NEVPT2 0.214239447

Molecule Identifiers

Property Value
CCDC ID OKAKER
SMILES OC(=O)CCn+ 1cc(O- )c2cc(Br)ccc2n1
InChI InChI=1S/C11H9BrN2O3/c12-7-1-2-9-8(5-7)10(15)6-14(13-9)4-3-11(16)17/h1-2,5-6H,3-4H2,(H-,13,15,16,17)
Molecular Formula C11 H9 Br1 N2 O3
CCDC URL https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=OKAKER&DatabaseToSearch=Published

Electronic Structure Methodology

Property Value
Electronic structure methodology SA-CASSCF
Correlation method SC-NEVPT2
Active Space 8,8
Basis Set Def2-TZVP
Excited State Software ORCA
Ground state functional B3LYP
Ground state basis set 6-31G*