Published April 29, 2026 | Version v1.0
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KEYROY

  • 1. University of Strathclyde

Description

Excited state energies, ORCA output file and optimised ground state geometry of KEYROY. Full dataset available here: BenchmarkSet1500.csv.

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Additional details

Related works

Is supplement to
Journal article: 10.1021/acs.joc.7b03227 (DOI)

Domain Specific Metadata

 

Excited States Properties

Property Value
E(S1) SA-CASSCF / eV 4.78
E(S2) SA-CASSCF / eV 4.987
E(T1) SA-CASSCF / eV 2.825
E(T2) SA-CASSCF / eV 4.544
f(S1) SA-CASSCF 0.048718487
f(S2) SA-CASSCF 0.503361647
E(S1) SC-NEVPT2 / eV 3.564
E(S2) SC-NEVPT2 / eV 3.676
E(T1) SC-NEVPT2 / eV 2.5
E(T2) SC-NEVPT2 / eV 3.453
f(S1) SC-NEVPT2 0.036330591
f(S2) SC-NEVPT2 0.371082218

Molecule Identifiers

Property Value
CCDC ID KEYROY
SMILES CC(C)(C)c1cc2cc(B3OC(C)(C)C(C)(C)O3)c3cc(cc4cc(B5OC(C)(C)C(C)(C)O5)c(c1)c2c34)C(C)(C)C
InChI InChI=1S/C36H48B2O4/c1-31(2,3)23-15-21-17-28(38-41-35(11,12)36(13,14)42-38)26-20-24(32(4,5)6)16-22-18-27(25(19-23)29(21)30(22)26)37-39-33(7,8)34(9,10)40-37/h15-20H,1-14H3
Molecular Formula C36 H48 B2 O4
CCDC URL https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=KEYROY&DatabaseToSearch=Published

Electronic Structure Methodology

Property Value
Electronic structure methodology SA-CASSCF
Correlation method SC-NEVPT2
Active Space 8,8
Basis Set Def2-TZVP
Excited State Software ORCA
Ground state functional B3LYP
Ground state basis set 6-31G*