Published April 29, 2026 | Version v1.0
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HUQBEA

  • 1. University of Strathclyde

Description

Excited state energies, ORCA output file and optimised ground state geometry of HUQBEA. Full dataset available here: BenchmarkSet1500.csv.

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Additional details

Related works

Is supplement to
Journal article: 10.1021/ja0281986 (DOI)

Domain Specific Metadata

 

Excited States Properties

Property Value
E(S1) SA-CASSCF / eV 5.306
E(S2) SA-CASSCF / eV 6.073
E(T1) SA-CASSCF / eV 4.24
E(T2) SA-CASSCF / eV 4.764
f(S1) SA-CASSCF 0.022124093
f(S2) SA-CASSCF 0.010285112
E(S1) SC-NEVPT2 / eV 3.887
E(S2) SC-NEVPT2 / eV 5.884
E(T1) SC-NEVPT2 / eV 3.951
E(T2) SC-NEVPT2 / eV 4.336
f(S1) SC-NEVPT2 0.01621012
f(S2) SC-NEVPT2 0.009965266

Molecule Identifiers

Property Value
CCDC ID HUQBEA
SMILES CC(C)N(C(C)C)P1(=S)C(c2ccccc2C(F)(F)F)P(=C1c1ccccc1C(F)(F)F)(N(C(C)C)C(C)C)N(C(C)C)C(C)C
InChI InChI=1S/C34H51F6N3P2S/c1-21(2)41(22(3)4)44(42(23(5)6)24(7)8)31(27-17-13-15-19-29(27)33(35,36)37)45(46,43(25(9)10)26(11)12)32(44)28-18-14-16-20-30(28)34(38,39)40/h13-26,31H,1-12H3
Molecular Formula C34 H51 F6 N3 P2 S1
CCDC URL https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=HUQBEA&DatabaseToSearch=Published

Electronic Structure Methodology

Property Value
Electronic structure methodology SA-CASSCF
Correlation method SC-NEVPT2
Active Space 8,8
Basis Set Def2-TZVP
Excited State Software ORCA
Ground state functional B3LYP
Ground state basis set 6-31G*