Published April 29, 2026 | Version v1.0
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QIHFIY

  • 1. University of Strathclyde

Description

Excited state energies, ORCA output file and optimised ground state geometry of QIHFIY. Full dataset available here: BenchmarkSet1500.csv.

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Additional details

Related works

Is supplement to
Journal article: 10.1021/om3009958 (DOI)

Domain Specific Metadata

 

Excited States Properties

Property Value
E(S1) SA-CASSCF / eV 3.201
E(S2) SA-CASSCF / eV 3.775
E(T1) SA-CASSCF / eV 3.12
E(T2) SA-CASSCF / eV 3.507
f(S1) SA-CASSCF 0.051075975
f(S2) SA-CASSCF 0.05666326
E(S1) SC-NEVPT2 / eV 3.458
E(S2) SC-NEVPT2 / eV 3.726
E(T1) SC-NEVPT2 / eV 3.418
E(T2) SC-NEVPT2 / eV 3.701
f(S1) SC-NEVPT2 0.059444801
f(S2) SC-NEVPT2 0.051896969

Molecule Identifiers

Property Value
CCDC ID QIHFIY
SMILES COC(=O)C(=C(c1ccccc1)Si (Cl)(N- c1c(cccc1C(C)C)C(C)C)C1=N+ (C(C)C)C(=C(C)N1C(C)C)C)Si (C)(C)C
InChI InChI=1S/C36H54ClN3O2Si2/c1-23(2)30-21-18-22-31(24(3)4)32(30)38-44(37,36-39(25(5)6)27(9)28(10)40(36)26(7)8)33(29-19-16-15-17-20-29)34(35(41)42-11)43(12,13)14/h15-26H,1-14H3
Molecular Formula C36 H54 Cl1 N3 O2 Si2
CCDC URL https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=QIHFIY&DatabaseToSearch=Published

Electronic Structure Methodology

Property Value
Electronic structure methodology SA-CASSCF
Correlation method SC-NEVPT2
Active Space 8,8
Basis Set Def2-TZVP
Excited State Software ORCA
Ground state functional B3LYP
Ground state basis set 6-31G*