Published April 29, 2026 | Version v1.0
Dataset Open

OYANAE

  • 1. University of Strathclyde

Description

Excited state energies, ORCA output file and optimised ground state geometry of OYANAE. Full dataset available here: BenchmarkSet1500.csv.

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Additional details

Related works

Is supplement to
Journal article: 10.3998/ark.5550190.0012.602 (DOI)

Domain Specific Metadata

 

Excited States Properties

Property Value
E(S1) SA-CASSCF / eV 2.963
E(S2) SA-CASSCF / eV 5.448
E(T1) SA-CASSCF / eV 2.813
E(T2) SA-CASSCF / eV 2.941
f(S1) SA-CASSCF 0.000611255
f(S2) SA-CASSCF 0.779497542
E(S1) SC-NEVPT2 / eV 3.207
E(S2) SC-NEVPT2 / eV 4.092
E(T1) SC-NEVPT2 / eV 3.091
E(T2) SC-NEVPT2 / eV 3.268
f(S1) SC-NEVPT2 0.000661524
f(S2) SC-NEVPT2 0.585557135

Molecule Identifiers

Property Value
CCDC ID OYANAE
SMILES CN(C(=Se )NC(=O)c1ccccc1)c1ccccc1
InChI InChI=1S/C15H14N2OSe/c1-17(13-10-6-3-7-11-13)15(19)16-14(18)12-8-4-2-5-9-12/h2-11H,1H3,(H,16,18,19)
Molecular Formula C15 H14 N2 O1 Se1
CCDC URL https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=OYANAE&DatabaseToSearch=Published

Electronic Structure Methodology

Property Value
Electronic structure methodology SA-CASSCF
Correlation method SC-NEVPT2
Active Space 8,8
Basis Set Def2-TZVP
Excited State Software ORCA
Ground state functional B3LYP
Ground state basis set 6-31G*