Published April 29, 2026 | Version v1.0
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IGACAV

  • 1. University of Strathclyde

Description

Excited state energies, ORCA output file and optimised ground state geometry of IGACAV. Full dataset available here: BenchmarkSet1500.csv.

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Additional details

Related works

Is supplement to
Journal article: 10.1107/S1600536808034193 (DOI)

Domain Specific Metadata

 

Excited States Properties

Property Value
E(S1) SA-CASSCF / eV 5.326
E(S2) SA-CASSCF / eV 5.448
E(T1) SA-CASSCF / eV 3.52
E(T2) SA-CASSCF / eV 4.205
f(S1) SA-CASSCF 0.141193909
f(S2) SA-CASSCF 0.312627944
E(S1) SC-NEVPT2 / eV 4.496
E(S2) SC-NEVPT2 / eV 4.73
E(T1) SC-NEVPT2 / eV 3.228
E(T2) SC-NEVPT2 / eV 4.085
f(S1) SC-NEVPT2 0.12540892
f(S2) SC-NEVPT2 0.257961758

Molecule Identifiers

Property Value
CCDC ID IGACAV
SMILES COc1ccc(cc1OC)N=Cc1cccc(c1)N(=O)=O
InChI InChI=1S/C15H14N2O4/c1-20-14-7-6-12(9-15(14)21-2)16-10-11-4-3-5-13(8-11)17(18)19/h3-10H,1-2H3
Molecular Formula C15 H14 N2 O4
CCDC URL https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=IGACAV&DatabaseToSearch=Published

Electronic Structure Methodology

Property Value
Electronic structure methodology SA-CASSCF
Correlation method SC-NEVPT2
Active Space 8,8
Basis Set Def2-TZVP
Excited State Software ORCA
Ground state functional B3LYP
Ground state basis set 6-31G*