Published April 29, 2026 | Version v1.0
Dataset Open

RIFHIX

  • 1. University of Strathclyde

Description

Excited state energies, ORCA output file and optimised ground state geometry of RIFHIX. Full dataset available here: BenchmarkSet1500.csv.

Files

Files (13.0 MB)

Name Size Download all
md5:ecf4f867dcd065c9161300612e3de36c
13.0 MB Download
md5:f25fc805846e80ef5aa9f34e9e586097
1.0 kB Download

Additional details

Related works

Is supplement to
Journal article: 10.1021/om960883w (DOI)

Domain Specific Metadata

 

Excited States Properties

Property Value
E(S1) SA-CASSCF / eV 2.613
E(S2) SA-CASSCF / eV 5.564
E(T1) SA-CASSCF / eV 2.466
E(T2) SA-CASSCF / eV 2.689
f(S1) SA-CASSCF 0.000190179
f(S2) SA-CASSCF 0.914195076
E(S1) SC-NEVPT2 / eV 2.761
E(S2) SC-NEVPT2 / eV 3.994
E(T1) SC-NEVPT2 / eV 2.627
E(T2) SC-NEVPT2 / eV 2.955
f(S1) SC-NEVPT2 0.000201006
f(S2) SC-NEVPT2 0.656177071

Molecule Identifiers

Property Value
CCDC ID RIFHIX
SMILES CN(C=Se )c1ccc(cc1)N(=O)=O
InChI InChI=1S/C8H8N2O2Se/c1-9(6-13)7-2-4-8(5-3-7)10(11)12/h2-6H,1H3
Molecular Formula C8 H8 N2 O2 Se1
CCDC URL https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=RIFHIX&DatabaseToSearch=Published

Electronic Structure Methodology

Property Value
Electronic structure methodology SA-CASSCF
Correlation method SC-NEVPT2
Active Space 8,8
Basis Set Def2-TZVP
Excited State Software ORCA
Ground state functional B3LYP
Ground state basis set 6-31G*