Published April 29, 2026 | Version v1.0
Dataset Open

POWDAI

  • 1. University of Strathclyde

Description

Excited state energies, ORCA output file and optimised ground state geometry of POWDAI. Full dataset available here: BenchmarkSet1500.csv.

Files

Files (52.4 MB)

Name Size Download all
md5:6f20c54cc4a59dc28ea689ac8f3a945d
52.4 MB Download
md5:1c32c3e2408443bfc159001c75a0f79d
2.2 kB Download

Additional details

Related works

Is supplement to
Journal article: 10.1021/ol501889g (DOI)

Domain Specific Metadata

 

Excited States Properties

Property Value
E(S1) SA-CASSCF / eV 4.73
E(S2) SA-CASSCF / eV 6.056
E(T1) SA-CASSCF / eV 1.922
E(T2) SA-CASSCF / eV 4.148
f(S1) SA-CASSCF 0.025256448
f(S2) SA-CASSCF 0.000172462
E(S1) SC-NEVPT2 / eV 4.775
E(S2) SC-NEVPT2 / eV 6.163
E(T1) SC-NEVPT2 / eV 2.12
E(T2) SC-NEVPT2 / eV 4.135
f(S1) SC-NEVPT2 0.025498346
f(S2) SC-NEVPT2 0.000175516

Molecule Identifiers

Property Value
CCDC ID POWDAI
SMILES O=N(=O)c1ccc(CN+ (O- )=C(C=Cc2ccccc2)c2ccccc2)cc1
InChI InChI=1S/C22H18N2O3/c25-23(17-19-11-14-21(15-12-19)24(26)27)22(20-9-5-2-6-10-20)16-13-18-7-3-1-4-8-18/h1-16H,17H2
Molecular Formula C22 H18 N2 O3
CCDC URL https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=POWDAI&DatabaseToSearch=Published

Electronic Structure Methodology

Property Value
Electronic structure methodology SA-CASSCF
Correlation method SC-NEVPT2
Active Space 8,8
Basis Set Def2-TZVP
Excited State Software ORCA
Ground state functional B3LYP
Ground state basis set 6-31G*