Published April 29, 2026 | Version v1.0
Dataset Open

MEPYAH

  • 1. University of Strathclyde

Description

Excited state energies, ORCA output file and optimised ground state geometry of MEPYAH. Full dataset available here: BenchmarkSet1500.csv.

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Additional details

Domain Specific Metadata

 

Excited States Properties

Property Value
E(S1) SA-CASSCF / eV 4.748
E(S2) SA-CASSCF / eV 4.89
E(T1) SA-CASSCF / eV 3.195
E(T2) SA-CASSCF / eV 3.772
f(S1) SA-CASSCF 0.001773553
f(S2) SA-CASSCF 0.568098415
E(S1) SC-NEVPT2 / eV 3.225
E(S2) SC-NEVPT2 / eV 3.869
E(T1) SC-NEVPT2 / eV 2.941
E(T2) SC-NEVPT2 / eV 3.295
f(S1) SC-NEVPT2 0.001445398
f(S2) SC-NEVPT2 0.37473606

Molecule Identifiers

Property Value
CCDC ID MEPYAH
SMILES Clc1ccc(cc1)N=NNc1ccccc1N(=O)=O
InChI InChI=1S/C12H9ClN4O2/c13-9-5-7-10(8-6-9)14-16-15-11-3-1-2-4-12(11)17(18)19/h1-8H,(H,14,15)
Molecular Formula C12 H9 Cl1 N4 O2
CCDC URL https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=MEPYAH&DatabaseToSearch=Published

Electronic Structure Methodology

Property Value
Electronic structure methodology SA-CASSCF
Correlation method SC-NEVPT2
Active Space 8,8
Basis Set Def2-TZVP
Excited State Software ORCA
Ground state functional B3LYP
Ground state basis set 6-31G*