Published April 29, 2026 | Version v1.0
Dataset Open

MUBCES

  • 1. University of Strathclyde

Description

Excited state energies, ORCA output file and optimised ground state geometry of MUBCES. Full dataset available here: BenchmarkSet1500.csv.

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Additional details

Related works

Is supplement to
Journal article: 10.1107/S1600536809026099 (DOI)

Domain Specific Metadata

 

Excited States Properties

Property Value
E(S1) SA-CASSCF / eV 4.528
E(S2) SA-CASSCF / eV 5.192
E(T1) SA-CASSCF / eV 2.539
E(T2) SA-CASSCF / eV 3.733
f(S1) SA-CASSCF 0.581440511
f(S2) SA-CASSCF 1.014993764
E(S1) SC-NEVPT2 / eV 3.381
E(S2) SC-NEVPT2 / eV 3.855
E(T1) SC-NEVPT2 / eV 2.326
E(T2) SC-NEVPT2 / eV 3.527
f(S1) SC-NEVPT2 0.434122021
f(S2) SC-NEVPT2 0.753542451

Molecule Identifiers

Property Value
CCDC ID MUBCES
SMILES CCN1C(=O)C(=CC=Cc2cc(OC)ccc2OC)C(=O)N(CC)C1=S
InChI InChI=1S/C19H22N2O4S/c1-5-20-17(22)15(18(23)21(6-2)19(20)26)9-7-8-13-12-14(24-3)10-11-16(13)25-4/h7-12H,5-6H2,1-4H3
Molecular Formula C19 H22 N2 O4 S1
CCDC URL https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=MUBCES&DatabaseToSearch=Published

Electronic Structure Methodology

Property Value
Electronic structure methodology SA-CASSCF
Correlation method SC-NEVPT2
Active Space 8,8
Basis Set Def2-TZVP
Excited State Software ORCA
Ground state functional B3LYP
Ground state basis set 6-31G*