Published April 29, 2026 | Version v1.0
Dataset Open

FIYVIT

  • 1. University of Strathclyde

Description

Excited state energies, ORCA output file and optimised ground state geometry of FIYVIT. Full dataset available here: BenchmarkSet1500.csv.

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Additional details

Related works

Is supplement to
Journal article: 10.1021/cm049686a (DOI)

Domain Specific Metadata

 

Excited States Properties

Property Value
E(S1) SA-CASSCF / eV 4.487
E(S2) SA-CASSCF / eV 4.632
E(T1) SA-CASSCF / eV 2.289
E(T2) SA-CASSCF / eV 3.163
f(S1) SA-CASSCF 1e-08
f(S2) SA-CASSCF 2.125938029
E(S1) SC-NEVPT2 / eV 2.503
E(S2) SC-NEVPT2 / eV 4.085
E(T1) SC-NEVPT2 / eV 2.185
E(T2) SC-NEVPT2 / eV 3.038
f(S1) SC-NEVPT2 9e-09
f(S2) SC-NEVPT2 1.149082891

Molecule Identifiers

Property Value
CCDC ID FIYVIT
SMILES CCCCCCC1=C(SC(=C1)C1=CC=CS1)C1=CC=C(S1)C1=CC=C(S1)C1=C(CCCCCC)C=C(S1)C1=CC=CS1
InChI InChI=1S/C36H38S6/c1-3-5-7-9-13-25-23-33(27-15-11-21-37-27)41-35(25)31-19-17-29(39-31)30-18-20-32(40-30)36-26(14-10-8-6-4-2)24-34(42-36)28-16-12-22-38-28/h11-12,15-24H,3-10,13-14H2,1-2H3
Molecular Formula C36 H38 S6
CCDC URL https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=FIYVIT&DatabaseToSearch=Published

Electronic Structure Methodology

Property Value
Electronic structure methodology SA-CASSCF
Correlation method SC-NEVPT2
Active Space 8,8
Basis Set Def2-TZVP
Excited State Software ORCA
Ground state functional B3LYP
Ground state basis set 6-31G*