Published April 29, 2026 | Version v1.0
Dataset Open

TECMEW

  • 1. University of Strathclyde

Description

Excited state energies, ORCA output file and optimised ground state geometry of TECMEW. Full dataset available here: BenchmarkSet1500.csv.

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Additional details

Related works

Is supplement to
Journal article: 10.1021/jacs.7b00873 (DOI)

Domain Specific Metadata

 

Excited States Properties

Property Value
E(S1) SA-CASSCF / eV 4.184
E(S2) SA-CASSCF / eV 4.343
E(T1) SA-CASSCF / eV 4.14
E(T2) SA-CASSCF / eV 4.29
f(S1) SA-CASSCF 0.00587256
f(S2) SA-CASSCF 0.024924245
E(S1) SC-NEVPT2 / eV 3.566
E(S2) SC-NEVPT2 / eV 3.578
E(T1) SC-NEVPT2 / eV 3.303
E(T2) SC-NEVPT2 / eV 3.447
f(S1) SC-NEVPT2 0.005005167
f(S2) SC-NEVPT2 0.02053324

Molecule Identifiers

Property Value
CCDC ID TECMEW
SMILES CC1(C)c2cccc(N3c4ccccc4Sc4ccccc34)c2Oc2c(cccc12)c1nc(nc(n1)c1ccccc1)c1ccccc1
InChI InChI=1S/C42H30N4OS/c1-42(2)30-20-13-19-29(41-44-39(27-15-5-3-6-16-27)43-40(45-41)28-17-7-4-8-18-28)37(30)47-38-31(42)21-14-24-34(38)46-32-22-9-11-25-35(32)48-36-26-12-10-23-33(36)46/h3-26H,1-2H3
Molecular Formula C42 H30 N4 O1 S1
CCDC URL https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=TECMEW&DatabaseToSearch=Published

Electronic Structure Methodology

Property Value
Electronic structure methodology SA-CASSCF
Correlation method SC-NEVPT2
Active Space 8,8
Basis Set Def2-TZVP
Excited State Software ORCA
Ground state functional B3LYP
Ground state basis set 6-31G*