Published April 29, 2026 | Version v1.0
Dataset Open

ONABAH

  • 1. University of Strathclyde

Description

Excited state energies, ORCA output file and optimised ground state geometry of ONABAH. Full dataset available here: BenchmarkSet1500.csv.

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Additional details

Related works

Is supplement to
Journal article: 10.1007/s10870-010-9836-1 (DOI)

Domain Specific Metadata

 

Excited States Properties

Property Value
E(S1) SA-CASSCF / eV 4.362
E(S2) SA-CASSCF / eV 5.858
E(T1) SA-CASSCF / eV 3.337
E(T2) SA-CASSCF / eV 4.101
f(S1) SA-CASSCF 0.145519874
f(S2) SA-CASSCF 0.639229706
E(S1) SC-NEVPT2 / eV 4.081
E(S2) SC-NEVPT2 / eV 4.373
E(T1) SC-NEVPT2 / eV 3.517
E(T2) SC-NEVPT2 / eV 4.164
f(S1) SC-NEVPT2 0.13614701
f(S2) SC-NEVPT2 0.477158612

Molecule Identifiers

Property Value
CCDC ID ONABAH
SMILES O=N(=O)c1ccccc1NC1=NN=C(O1)c1ccccc1
InChI InChI=1S/C14H10N4O3/c19-18(20)12-9-5-4-8-11(12)15-14-17-16-13(21-14)10-6-2-1-3-7-10/h1-9H,(H,15,17)
Molecular Formula C14 H10 N4 O3
CCDC URL https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=ONABAH&DatabaseToSearch=Published

Electronic Structure Methodology

Property Value
Electronic structure methodology SA-CASSCF
Correlation method SC-NEVPT2
Active Space 8,8
Basis Set Def2-TZVP
Excited State Software ORCA
Ground state functional B3LYP
Ground state basis set 6-31G*