Published April 29, 2026 | Version v1.0
Dataset Open

SOXQIH

  • 1. University of Strathclyde

Description

Excited state energies, ORCA output file and optimised ground state geometry of SOXQIH. Full dataset available here: BenchmarkSet1500.csv.

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Additional details

Related works

Is supplement to
Journal article: 10.1021/jo501952t (DOI)

Domain Specific Metadata

 

Excited States Properties

Property Value
E(S1) SA-CASSCF / eV 5.627
E(S2) SA-CASSCF / eV 7.256
E(T1) SA-CASSCF / eV 5.392
E(T2) SA-CASSCF / eV 6.224
f(S1) SA-CASSCF 0.001655128
f(S2) SA-CASSCF 0.00378332
E(S1) SC-NEVPT2 / eV 5.853
E(S2) SC-NEVPT2 / eV 6.832
E(T1) SC-NEVPT2 / eV 5.623
E(T2) SC-NEVPT2 / eV 6.168
f(S1) SC-NEVPT2 0.00172155
f(S2) SC-NEVPT2 0.003561899

Molecule Identifiers

Property Value
CCDC ID SOXQIH
SMILES OC1CCNH2+ C(CC(=O)O- )C1O
InChI InChI=1S/C7H13NO4/c9-5-1-2-8-4(7(5)12)3-6(10)11/h4-5,7-9,12H,1-3H2,(H,10,11)
Molecular Formula C7 H13 N1 O4
CCDC URL https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=SOXQIH&DatabaseToSearch=Published

Electronic Structure Methodology

Property Value
Electronic structure methodology SA-CASSCF
Correlation method SC-NEVPT2
Active Space 8,8
Basis Set Def2-TZVP
Excited State Software ORCA
Ground state functional B3LYP
Ground state basis set 6-31G*