Published April 29, 2026 | Version v1.0
Dataset Open

COGNOD01

  • 1. University of Strathclyde

Description

Excited state energies, ORCA output file and optimised ground state geometry of COGNOD01. Full dataset available here: BenchmarkSet1500.csv.

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Additional details

Related works

Is supplement to
Journal article: 10.1364/JOSAB.33.00E160 (DOI)

Domain Specific Metadata

 

Excited States Properties

Property Value
E(S1) SA-CASSCF / eV 4.837
E(S2) SA-CASSCF / eV 5.383
E(T1) SA-CASSCF / eV 3.098
E(T2) SA-CASSCF / eV 3.215
f(S1) SA-CASSCF 2.243681818
f(S2) SA-CASSCF 0.043909231
E(S1) SC-NEVPT2 / eV 3.274
E(S2) SC-NEVPT2 / eV 3.836
E(T1) SC-NEVPT2 / eV 2.703
E(T2) SC-NEVPT2 / eV 2.812
f(S1) SC-NEVPT2 1.518700242
f(S2) SC-NEVPT2 0.03129025

Molecule Identifiers

Property Value
CCDC ID COGNOD01
SMILES CCN(CC)c1ccc(C=CC(=O)C=Cc2ccc(cc2)N(CC)CC)cc1
InChI InChI=1S/C25H32N2O/c1-5-26(6-2)23-15-9-21(10-16-23)13-19-25(28)20-14-22-11-17-24(18-12-22)27(7-3)8-4/h9-20H,5-8H2,1-4H3
Molecular Formula C25 H32 N2 O1
CCDC URL https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=COGNOD01&DatabaseToSearch=Published

Electronic Structure Methodology

Property Value
Electronic structure methodology SA-CASSCF
Correlation method SC-NEVPT2
Active Space 8,8
Basis Set Def2-TZVP
Excited State Software ORCA
Ground state functional B3LYP
Ground state basis set 6-31G*