Published April 29, 2026 | Version v1.0
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KADNEI

  • 1. University of Strathclyde

Description

Excited state energies, ORCA output file and optimised ground state geometry of KADNEI. Full dataset available here: BenchmarkSet1500.csv.

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Additional details

Related works

Is supplement to
Journal article: 10.1107/S0108270188011345 (DOI)

Domain Specific Metadata

 

Excited States Properties

Property Value
E(S1) SA-CASSCF / eV 5.544
E(S2) SA-CASSCF / eV 5.741
E(T1) SA-CASSCF / eV 3.3
E(T2) SA-CASSCF / eV 3.345
f(S1) SA-CASSCF 1.656140532
f(S2) SA-CASSCF 0.054887199
E(S1) SC-NEVPT2 / eV 3.395
E(S2) SC-NEVPT2 / eV 4.169
E(T1) SC-NEVPT2 / eV 3.159
E(T2) SC-NEVPT2 / eV 3.272
f(S1) SC-NEVPT2 1.014277222
f(S2) SC-NEVPT2 0.039864144

Molecule Identifiers

Property Value
CCDC ID KADNEI
SMILES CN1CC(=Cc2ccc(cc2)N(C)C)C(=O)C(C1)=Cc1ccc(cc1)N(C)C
InChI InChI=1S/C24H29N3O/c1-25(2)22-10-6-18(7-11-22)14-20-16-27(5)17-21(24(20)28)15-19-8-12-23(13-9-19)26(3)4/h6-15H,16-17H2,1-5H3
Molecular Formula C24 H29 N3 O1
CCDC URL https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=KADNEI&DatabaseToSearch=Published

Electronic Structure Methodology

Property Value
Electronic structure methodology SA-CASSCF
Correlation method SC-NEVPT2
Active Space 8,8
Basis Set Def2-TZVP
Excited State Software ORCA
Ground state functional B3LYP
Ground state basis set 6-31G*