Published April 29, 2026 | Version v1.0
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HAKSIW

  • 1. University of Strathclyde

Description

Excited state energies, ORCA output file and optimised ground state geometry of HAKSIW. Full dataset available here: BenchmarkSet1500.csv.

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Additional details

Related works

Is supplement to
Journal article: 10.1016/j.jorganchem.2004.07.042 (DOI)

Domain Specific Metadata

 

Excited States Properties

Property Value
E(S1) SA-CASSCF / eV 4.901
E(S2) SA-CASSCF / eV 5.106
E(T1) SA-CASSCF / eV 4.358
E(T2) SA-CASSCF / eV 4.822
f(S1) SA-CASSCF 0.018416342
f(S2) SA-CASSCF 4.7e-08
E(S1) SC-NEVPT2 / eV 3.705
E(S2) SC-NEVPT2 / eV 3.94
E(T1) SC-NEVPT2 / eV 3.636
E(T2) SC-NEVPT2 / eV 3.864
f(S1) SC-NEVPT2 0.013922665
f(S2) SC-NEVPT2 3.6e-08

Molecule Identifiers

Property Value
CCDC ID HAKSIW
SMILES CC(C)P(C(C)C)c1c(F)c(P(c2ccccc2)c2ccccc2)c(P(C(C)C)C(C)C)c(F)c1P(c1ccccc1)c1ccccc1
InChI InChI=1S/C42H48F2P4/c1-29(2)45(30(3)4)39-37(43)42(48(35-25-17-11-18-26-35)36-27-19-12-20-28-36)40(46(31(5)6)32(7)8)38(44)41(39)47(33-21-13-9-14-22-33)34-23-15-10-16-24-34/h9-32H,1-8H3
Molecular Formula C42 H48 F2 P4
CCDC URL https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=HAKSIW&DatabaseToSearch=Published

Electronic Structure Methodology

Property Value
Electronic structure methodology SA-CASSCF
Correlation method SC-NEVPT2
Active Space 8,8
Basis Set Def2-TZVP
Excited State Software ORCA
Ground state functional B3LYP
Ground state basis set 6-31G*